GCSE · Chemistry · AQA · Spec 8462

Flame emission spectroscopy

From sample to spectrum

Follow what happens to the emitted light and what the result tells you.

  1. Sample enters the flameIn flame emission spectroscopy, the sample is put into a flame so that it gives out light.
  2. Light reaches the spectroscopeThe emitted light is passed through a spectroscope so it can be analysed.
  3. A line spectrum appearsThe instrument produces a line spectrum rather than relying only on the visible flame colour.
  4. Compare with referencesThe result can be interpreted by comparing it with an appropriate reference set presented in the same form.
  5. Identify the ionsAnalysis of the line spectrum can reveal which metal ions are present in the solution.
  6. Measure concentrationThe line spectrum can also be used to measure the concentrations of metal ions in the solution.

Five flame-test colours

Learn each ion and colour as one pair.

Flame test or flame emission spectroscopy?

Flame testvsFlame emission spectroscopy

Both involve a flame, but the evidence you interpret is different.

Focus

Result used

Flame test

Distinctive flame colour

Flame emission spectroscopy

Line spectrum

The insight

A flame test uses the observed colour, whereas spectroscopy analyses emitted light as a line spectrum.

What it can identify

Flame test

Some metal ions

Flame emission spectroscopy

Metal ions in solutions

Concentration

Flame test

Not part of the simple flame test

Flame emission spectroscopy

Can be measured

Mixtures

Flame test

Some flame colours can be masked

Flame emission spectroscopy

Analyse the line spectrum

Method type

Flame test

Flame test

Flame emission spectroscopy

Instrumental method

Interpret the result

Use only the supplied reference information.

An unknown solution produces a line spectrum that exactly matches Reference B. The supplied reference set labels B as calcium. What should you identify in the unknown?

Relationship matrix

Tap any cell to reveal it. Tap a column header to read one property down every item.

OutputIdentificationConcentrationMixture issue
Simple flame testColour observation
Flame emission spectroscopyInstrumental analysis

Each cell hides a short answer and the reason behind it. Predict before you tap.

Spectroscopy essentials

Keep the method, output and interpretation vocabulary precise.

WHAT YOU'VE LEARNED

A quick recap of today's lesson.

Use flame colours and line spectra to identify metal ions and analyse solutions.

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How this lesson was checked. This AQA GCSE Chemistry (specification 8462)lesson was published through Lightbulb Learning's human-designed editorial process — the educational standards, accuracy rules and publication checks it must pass were authored and approved by Philip Halpin. It passed subject-specific assessment, automated educational checks and technical publication verification before going live (publication checks completed 12 August 2026). Published pages are monitored, human spot-checking is ongoing across the lesson library, and anything found wrong is corrected or withdrawn. How our lessons are made and checked. Spotted a mistake? Email hello@lightbulblearning.co and we'll review it.